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Self-assembly behavior of poly(γ-benzyl l-glutamate)-graft-poly(ethylene glycol) (PBLG-g-PEG) in ethanol medium was studied by transmission electron microscopy (TEM), scanning electron microscopy (SEM), laser light scattering (LLS), and circular dichroism (CD). The experimental results revealed that the conformation change of the polypeptide graft copolymer exerts marked effect on its self-association...
Effect of external electrical field on phase equilibrium was reported for poly(γ-benzyl l-glutamate) (PBLG) in a mixed solvent containing denaturant acid where a helix–coil transition coupled anisotropic–isotropic transition exists. The experimental results revealed that the anisotropic phase and helix conformation can be stabilized when an external electrical field is applied. In the presence of...
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