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In article number 1707234, NH4TFSI is presented as a functional electrolyte additive to alleviate the passivation of Li2S for Li‐S batteries under lean electrolyte conditions by Yuyan Shao, Jun Liu, and co‐workers. This additive enhances the dissociation of Li2S and facilitates the homogeneous formation of Li2S particles, which significantly promotes the reversibility and reaction kinetics of sulfur...
Reducing the electrolyte amount is critical for the high specific energy of lithium–sulfur (Li–S) batteries in practice. The reduced electrolyte condition (a so‐called “lean electrolyte”) raises a complex situation for sulfur redox reactions since the reactions rely on the electrolyte mediation. The insulating nature of discharge product Li2S and its uncontrollable accumulation (passivation) at the...
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