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A bipolar electrode is quite unconventional as it behaves simultaneously as an anode and a cathode in contrast to a classic electrochemical setup where the electron transfer reactions are promoted on two different electrodes. The driving force is the polarization potential established between the solution and the bipolar electrode, that allows a wireless electrochemical addressing. In the past decade...
The site selective electrodeposition of silver metal onto a conducting object such as carbon microtubes (CMTs) in an electrolytic solution could be achieved by means of bipolar electrochemistry. Two half reactions are simultaneously carried out at both extremities of the CMT, which act as a bipolar electrode. The thermodynamic threshold value of the process, which consists in metal electroreduction...
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