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Ground state electronic absorption and luminescence spectra for M III (OEP)(Nc) (M=La, Eu, Lu; OEP=2,3,7,8,12,13,17,18-octaethylporphyrinate; Nc=2,3-naphthalocyaninate) and Ce(OEP)(Nc) are recorded and comparatively studied. Strong π–π interactions are present in these highly π-conjugated systems. The central metal ions seem to play no direct role either in the absorption spectra or in the...
The resonance or near-resonance Raman spectroscopic data in the range of 500–1800 cm −1 of a series of nineteen naphthalocyaninato (Nc), phthalocyaninato (Pc) and/or porphyrinato (Por) rare earth sandwich complexes including double-deckers M[Pc(OC 8 H 17 ) 8 ] 2 (M=Nd, Ce, Eu, Er), M(Nc*) 2 [M=Pr, Nd, Eu; Nc*=Nc( t Bu) 4 , Nc(SC 12...
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