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In article number 2005821, Bolong Huang, Yanguang Li, and co‐workers report the preparation of alloyed Pd–Ag nanowires for electrochemical CO2 reduction to formate with high selectivity and stability in aqueous solution, which is due to the markedly enhanced CO tolerance and selective stabilization of key reaction intermediates on the alloy nanowires.
Palladium can enable the electrochemical CO2 reduction to formate with nearly zero overpotential and good selectivity. However, it usually has very limited stability owing to CO poisoning from the side reaction intermediate. Herein, it is demonstrated that alloying palladium with silver is a viable strategy to significantly enhance the electrocatalytic stability. Palladium–silver alloy nanowires are...
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