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The structure of the complex of 5-sulfasalicilato zirconium (IV) phthalocyanine was studied with 1D, 2D 1 H NMR and 1 H– 14 N NMR spectroscopy and electro spray ionization mass spectrometry (ESI-MS). The computer models of this complexes was created with program HyperChem 7.0. The strong correlation between geometrically optimized molecule structure and location of characteristic...
The series of new zirconium(IV) and hafnium(IV) phthalocyanines with various β-dicarbonyl ligands were prepared via direct interaction between di(chloro)zirconium(IV) or hafnium(IV) phthalocyanines and free β-diketones and also with 4-benzoyl-3-methyl-1-phenyl-2-pyrazolin-5-one. The structure of the obtained bis(β-dicarbonilato) zirconium(IV) and hafnium(IV) phthalocyanines was studied by two dimension...
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