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Cu2ZnSnS4 (CZTS) powder with kesterite structure was prepared by ball milling of mixture of Cu2S, ZnS and SnS2 powders for more than 15h. By dispersing the milled CZTS powder in a Cu-, Zn- and Sn-chalcogenide precursor solution, a hybrid ink was fabricated. With the hybrid ink, a precursor CZTS film was deposited on Mo coated soda-lime glass by spin-coating. In order to obtain Cu2ZnSn(S,Se)4 (CZTSSe)...
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