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The unusual suspects: Depending on co‐ligands Ln and the effects of substituents (R), the well‐known triazenides [N(NR)2]− may act as EPR detectable coordinated triazenyl ligands, [N(NR)2]. (see scheme). They are thus new non‐innocent ligands and are related to the hitherto unused non‐innocent nitrogen dioxide ligand, [NO2]..
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