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A novel one-dimensional silver(I) complex, derived from 2-hydroxypyridine with Ag 2 O in an ammonia solution, have been prepared and structurally characterized. Each Ag atom in the complex is three-coordinate in a T-shaped geometry with two phenolate O atoms and one pyridine N atom. Adjacent Ag atoms are linked by Ag–Ag interactions, forming an Ag 4 unit. The Ag 4 units are...
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