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The understanding of the external enhancement effects from host matrixes on thermally activated delayed fluorescence (TADF) emitters is crucial but incomprehensive at present. Herein, a series of phosphine oxide (PO) acceptors mDBSOSPO (m= 2, 3, and 4, corresponding to PO substitution position) and 4,4'‐bis(9‐carbazolyl)‐2,2'‐dimethylbiphenyl (CDBP) as donor is used to construct CDBP:mDBSOSPO exciplex...
Highly efficient lepidine‐based phosphorescent iridium(III) complexes with pentane‐2,4‐dione or triazolpyridine as ancillary ligands have been designed and prepared by a newly developed facile synthetic route. Fluorine atoms and trifluoromethyl groups have been introduced into the different positions of ligand, and their influence on the photophysical properties of complexes has been investigated...
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