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A double‐walled tetrahedral metal‐organic cage assembled in solution from silver(I), 2‐formyl‐1,8‐naphthyridine, halide, and a threefold‐symmetric triamine. The AgI4X clusters at its vertices each bring together six naphthyridine‐imine moieties, leading to a structure in which eight tritopic ligands bridge four clusters in an (AgI4X)4L8 arrangement. Four ligands form an inner set of tetrahedron walls...
A double‐walled tetrahedral metal‐organic cage assembled in solution from silver(I), 2‐formyl‐1,8‐naphthyridine, halide, and a threefold‐symmetric triamine. The AgI4X clusters at its vertices each bring together six naphthyridine‐imine moieties, leading to a structure in which eight tritopic ligands bridge four clusters in an (AgI4X)4L8 arrangement. Four ligands form an inner set of tetrahedron walls...
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