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A Zn(II)-based porous coordination polymer (PCP) {[Zn2(ppt)2(fdc)(H2O)2]·2DMF}n (1) (H2fdc=9H-fluorene-2,7-dicarboxylic acid, Hppt=3-(2-pyrazinyl)-5-(4-pyridyl)-1,2,4-triazole) has been synthesized under hydrothermal conditions. The resulting PCP shows a 7-fold interpenetrated 3D structure that can be simplified as a diamond-like structure with Zn1 as node and fdc− and Zn(ppt)2 as spacers. It exhibits...
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