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Subsolidus (450–480°C) phase relations in the Tl2MoO4-Pr2(MoO4)3-Hf(MoO4)2 system have been studied by X-ray diffraction. The system has been shown to contain molybdates with the compositions Tl5PrHf(MoO4)6 (5: 1: 2), TlPrHf0.5(MoO4)3 (1: 1: 1), and Tl2PrHf2(MoO4)6.5 (2: 1: 4). Single crystals of the double molybdate TlPr(MoO4)2 have been grown for the first time from high-temperature solutions through...
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