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Two mono anchoring dye molecules were bridged together to give a new di-anchoring bis-merocyanine dye which possessed a non-planar conformation on a TiO 2 surface, a feature that impedes intermolecular aggregation of the dye in the adsorbed state. This dye also showed enhanced molar absorptivity and increased adsorption on TiO 2 . A dye sensitized solar cell based on the bis-merocyanine...
The chemical shift assignments of pinacyanol (1,1-diethyl-2,2′-carbocyanine) iodide were obtained by means of 1-D ( 1 H and 13 C) and 2-D ( 1 H– 1 H COSY, 13 C– 1 H COSY, and HMBC) NMR and theoretical calculations (GIAO-HF and GIAO-DFT using the 6-31+G(d,p) basis set). An optimized structure, calculated using B3LYP/6-31G(d), of the stable conformer gave...
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