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A robust self‐template strategy is used for facile and large‐scale synthesis of porous multishell gold with controllable shell number, sphere size, and in situ surface modification. The process involved the rapid reduction of novel Au‐melamine colloidal templates with a great amount of NaBH4 in presence of poly(sodium‐p‐styrenesulfonate) (PSS). After soaking the templates in other metal salt solution,...
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