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Alternating multilayers assembled stepwise with two prototype polyelectrolytes, i.e. poly(allylamine) hydrochloride (PAA) and poly(vinyl sulfate) potassium salt (PVS), have been examined by means of reflection-absorption infrared (RAIR) spectroscopy and atomic force microscopy (AFM). The growth step revealed by the RAIR spectroscopy was in good agreement with the ellipsometric data. The RAIR spectral...
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