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In this study, we have investigated CuO doping effect on PZT-PZNN thick film for lower temperature sintering of multi-layer structure energy harvesting system. We prepared 0.69PZT-0.31PZNN powder, slurry, and green sheet to manufacture thick film ceramics with different doping amount of CuO. Various amount of CuO (0, 1, 2 and 3 mol%) were inserted into piezoelectric material composition of (Zr0.47...
0.69Pb(Zr0.47Ti0.53)O3-0.31Pb[(Zn0.4Ni0.6)1/3Nb2/3]O3 [0.69PZT–0.31PZNN] piezoelectric thick film was fabricated as a high energy density piezoelectric material by tape casting process. The effect of ball milling condition on properties of 0.69PZT-0.31PZNN thick film was investigated. As a result, the condition using 10 mm diameter zirconium balls for 48 hours is optimized ball milling condition....
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