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The industrialization of lithium–sulfur (Li–S) batteries is simultaneously impeded by the shuttle effect of lithium polysulfides and dendrites growth on lithium anode. To address both issues, a novel sulfiphilic and lithiophilic interlayer of Mo2N quantum dots decorated N‐doped graphene‐nanosheet (Mo2N@NG) are presented on polypropylene separator via a facile scalable method. Benefiting from the strong...