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A new series of complexes of 2-hydroxy-3,5-dimethyl acetophenone oxime (HDMAOX) with Cu(II), Co(II), Ni(II) and Pd(II) have been prepared and characterized by different physical techniques. Infrared spectra of the complexes indicate deprotonation and coordination of the phenolic OH. It also confirms that nitrogen atom of the oximino group contributes to the complexation. Electronic spectra and magnetic...
Cobalt(II) complexes of reduced glutathione (GSH) of general composition Na[Co(L)(X)]·nH2O (where H2L=GSH; X=Cl−, NO3−, NCS−, CH3CO2−, HCO2−, ClO4− and n=0–4) have been synthesized and characterised by elemental analyses, vibrational spectra, electronic spectra, magnetic susceptibility measurements, thermal studies and molecular modeling studies. Electronic spectra indicate planar geometry for...
Novel complexes of Co(II), Ni(II), Cu(II) and Pd(II) with the new ligand [N,N'-bis(2-carboxy-1-oxo-phenelenyl)ethylenediamine] (H 2 L) have been synthesized and characterized on the basis of elemental analyses, magnetic susceptibility, thermal, infrared, electronic, 1 H NMR and EPR spectral studies. Infrared and 1 H NMR spectra show that H 2 L acts as a binegative tetradentate...
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