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Bifunctional Au@Ni core–satellite nanostructures synthesized by a one‐step assembly method were employed for in situ surface‐enhanced Raman spectroscopic (SERS) monitoring of Ni‐catalyzed C−C bond‐forming reactions. Surprisingly, the reaction that was thought to be an Ullmann‐type self‐coupling reaction, was found to be a cross‐coupling reaction proceeding by photoinduced aromatic C−H bond arylation...
Ein biegsames Polymer für die selektive Meerwasserspaltung: Die Einführung eines monomeren Manganporphyrins, das normalerweise katalytisch inaktiv ist, in einen biegsamen Poly(terthiophen)‐Film ergibt einen bemerkenswerten lichtunterstützten Wasseroxidationskatalysator mit einem effektiven Überpotential für die Wasseroxidation von nur 0.09 V. Der Katalysator erzeugt in Meerwasser bei 0.9 V (gegen...
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