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Aza‐dipyrromethene boron difluoride (Aza‐BODIPY) dyes have attracted much interest in recent decades. In this manuscript, we provide a facile way to access pyridine‐substituted pyrroles. A series of 1/7‐pyridinyl and pyridinium near‐infrared (NIR) Aza‐BODIPYs with/without rigidity were constructed and their spectroscopic properties were extensively investigated. These pyridinyl Aza‐BOIDIPYs displayed...
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