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The Li3Mg2(Sb1−xVx)O6 (0.01 ≤ x ≤ 0.04) ceramics have been synthesized by the solid-state reaction method. The effects of V5+ ion substitution on the sinterability, phase composition and microwave dielectric properties of Li3Mg2(Sb1−xVx)O6 ceramics were investigated. The dehiscence and secondary phase in Li3Mg2SbO6-based ceramics could be effectively inhibited by partial substitution of V5+ on the...