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The kinetic and mechanistic studies of homogeneously Rh(III)-catalysed oxidation of D-xylose and L-sorbose by Nbromoacetamide (NBA) in perchloric acid medium were carried out at 40 °C. The reactions were first-order with respect to each of [NBA], [Rh(III)] and [H+] and zero-order in [sugar]. Variation of [Cl−] showed positive effect while variation of [Hg(OAc)2] showed negative effect on the rate...
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