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The mechanical strength of solid‐state electrolytes is crucial for applications in solid‐state batteries (eg block lithium dendrites and withhold the stress due to volume expansion of the electrode). We determined the flexural strength of doped Li7La3Zr2O12 (Li7La2.75Ca0.25Zr1.75Nb0.25O12, LLCZN) garnet type electrolyte as ~8.6 ± 1.5 MPa to ~51.5 ± 4.8 MPa as functions of porosity and grain size....
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