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The effect of TiO x on the bonding of CO test molecules to different Rh surfaces has been investigated in model systems under UHV conditions. The TiO x overlayers had a twofold effect both on Rh nanoparticles and Ar + -ion sputtered Rh films prepared on TiO 2 (110). They suppressed the uptake of molecular CO by a site blocking mechanism. In the other mechanism the recombinative...
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