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Employing the multicarboxylate and N-donor mixed ligands to react with Zn(NO3)2·6H2O affords a new 3D compound [Zn3(HBPTC)2(bmp)2(H2O)2]·2H2O (1) (H4BPTC = biphenyl-3,3′,4,4′-tetracarboxylic acid, bmp = 3,6-bis(imidazol-1-yl)pyridazine). Structural analyses show that compound 1 possesses a (4,4)-connected neutral framework bearing rare NbO-x-d subnets, and it represents the first replica of the theoretically...
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