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A practical and efficient protocol for the syntheses of 6‐substituted 2‐bromopyridine compounds has been developed by using a selective copper‐catalyzed C–N bond‐forming reaction between 2,6‐dibromopyridine and a range of amines. The major advantage of this protocol is the complete control of selectivity of the pyridine bromine atom for the C–N cross‐coupling reaction. There are few reported syntheses...
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