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The heat contents (HT − H298K) of Sc5Si3 and ScSi in the Sc–Si system were measured by drop calorimetry method from 400 to 1,200 °C in the present work. Based on the critically reviewed thermodynamic properties and phase diagram data from the literature and the present work, the Sc–Si system was assessed by means of the CALPHAD (CALculation of PHAse Diagram) approach. The Gibbs energies of solution...
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