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A biomimic pH‐sensitive polymeric prodrug based on branched polyethylenimine‐graft‐12‐acryloyloxy dodecyl phosphorylcholine and 6‐maleimidocaproyl‐doxorubicin is rationally designed and successfully synthesized. This polymeric prodrug can spontaneously self‐assemble into spherical nanostructures in aqueous solution. The in vitro drug release results imply that this polymeric prodrug can maintain stable...
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