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Janus Au-mesoporous silica nanoparticles were used as scaffolds to design an integrated electrochemical biorecognition-signaling system. A proof of concept of this strategy, based on the face-selective functionalization of the anisotropic colloid, involves the covalent immobilization of horseradish peroxidase on the mesoporous silica face as enzymatic signaling element, as well as the modification...
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