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The (001) crystal surface of RbTiOPO4 (RTP) were bombarded by Ar+ ion during different times (2–20 min) and the resulting chemical modification on surface has been studied by X-ray photoelectron spectroscopy (XPS) and first-principles calculations. Ion bombardment can lead to great structural modification on the surface of RTP crystal. Reduction of Ti4+ ions to the lower valence state (Ti3+) and formation...
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