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Gas electron diffraction at a temperature T of 641(5) K is used to study the structure of an N,N′-ethylenebis(salicylaldiminato) zinc(II) molecule, ZnO2N2C16H14, further Zn(salen). The structure of a gaseous Zn(salen) complex has C2 symmetry and is characterized by a substantial turn of two chelating fragments of the ligand with respect to each other, and also by a big difference in the length of...
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