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Two kinds of ethylene-α-octene copolymers (ethylene-α-octene block copolymer, OBC, and ethylene-α-octene random copolymer, ORC) and their composites with MWCNTs were investigated by means of various solid-state NMR techniques. 13C MAS NMR revealed that there were only orthorhombic crystals in OBC composites, which resulted in stronger volume exclusion effect towards MWCNTs than that in ORC composites...
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