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The rotational spectrum of the acetic acid-fluoroacetic acid bimolecule was measured by using a pulsed jet Fourier transform microwave spectrometer. One conformer, in which fluoroacetic acid is in trans form, has been observed. The rotational transitions are split into two component lines, due to the internal rotation of the methyl group of acetic acid. From these splittings, the corresponding V3...
The microwave spectrum of the van der Waals complex CF3ClAr has been investigated by pulsed jet Fourier transform microwave spectroscopy. The observed spectra of the 35Cl and 37Cl isotopologues are typical of asymmetric tops, with rotational constants A, B, C=3373.118(4), 988.2529(4), 879.5788(3) and 3286.66(4), 985.50(3), 871.359(8)MHz, respectively. The Ar atom is almost “L-shaped” with respect...
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