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The local lattice distortions of the various rhombic Ru3+ centres (A, A′, B, B′, X and X′) in AgX (X=Cl and Br) are quantitatively investigated from the perturbation calculations of the anisotropic g factors and hyperfine structure constants for a 4d5 ion in rhombically distorted octahedra. Centre A or A′ is assigned to the substitutional Ru3+ on Ag+ site associated with one nearest neighbor silver...
The local structures and spin Hamiltonian parameters (SHPs, g factors, hyperfine structure constants and superhyperfine parameters) are theoretically investigated for the two orthorhombic Rh2+centers R4 and R5 in AgCl microcrystals. Center R4 is ascribed to the impurity Rh2+substituted for Ag+ with two H2O molecules substituted for the nearest neighbor ligands Cl− along the [100] and [010] axes, each...
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