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We demonstrate the electrochemical characteristics of the, poorly described in the literature, mixed-valence proton conducting solid borotungstic acid single crystal, H5BW12O40xH2O, in the absence of liquid electrolyte phase. We performed electrochemical measurements in an all-solid cell with a gold fiber ultramicrodisk (diameter 10, 25, and 40 μm) working electrode, a silver semi-reference disk...
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