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The oxidation of the Fe-5Cr-5Si and Fe-10Cr-5Si alloys has been examined under 1 and 10−20atm O2 at 700°C. In all cases the Cr additions improved the oxidation resistance of the Fe-5Si alloy by forming protective external scales rich in Cr- and Si-oxides, except for the oxidation of Fe-5Cr-5Si under the low oxygen pressure. Their scaling behavior has been interpreted using the kinetic diagrams of...
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