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Synthetic gadolinium(III)porphyrins with various achiral β-diketonates as axial ligands in benzene solutions extracted chiral α-amino acids and dipeptides from aqueous phases to give intense induced CD peaks in the Soret region via 1:1 supercomplexation. Their CD spectral shapes were dependent on the stereochemistry at the α-positions of amino acids and of the C-terminal components of dipeptides:...
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