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The growth of ultrathin Cr overlayers on SrTiO 3 (100) was studied by X-ray photoelectron spectroscopy, scanning tunneling microscopy, and transmission electron microscopy. It is found that the metal–oxide interaction strongly depends on the deposition temperature. At T<600°C, the interfaces are atomically sharp. Local charge transfer happens between the interfacial Cr adatoms and the topmost...
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