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The oxidation of cis‐[Pt(NH3)2(OAc)2] with H2O2 yields a mixture of two isomers: ctc‐[Pt(NH3)2(OH)2(OAc)2] and ctc‐[Pt(NH3)2(OH)(OAc)(OH)(OAc)]. Following modification with 4‐phenylbutyric (PhB) anhydride, two isomers were separated and characterized; the symmetric ctc‐[Pt(NH3)2(PhB)2(OAc)2] (1) and the nonsymmetric ctc‐[Pt(NH3)2(PhB)(OAc)(PhB)(OAc)] (2). They differ in their log P values and despite...
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