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Die Entwicklung hochselektiver Vorschriften ist eines der Kernziele der organischen Chemie. Unter den bekannten organischen Transformationen sind Carbonylierungen eine ideale Wahl für die Herstellung von Verbindungen mit Carbonylgruppen. In diesem Aufsatz werden die jüngsten Erfolge bei der Kontrolle der Selektivität von Carbonylierungsreaktionen zusammengefasst. Der Einfluss der Liganden, Lösungsmittel...
After decades of development, carbonylation reactions have become one of the most powerful tools in modern organic synthesis. However, the requirement of CO gas limits the applications of such reactions. Reported herein is a versatile and practical protocol for carbonylative reactions which rely on the cooperation of phenyl formate and nonaflate, and the generation of CO in situ. This protocol has...
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