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Elucidating the effects of crystallization‐induced blue‐shift emission of a newly synthesized di‐boron complex (DBC) by enhanced photoluminescence (PL) and electrochemiluminescence (ECL) in the annihilation pathway was realized for the first time. The 57 nm blue‐shift and great enhancement in the crystalline lattice relative to the DBC solution were attributed to the restriction of intramolecular...
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