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Thermoelectric properties of Au-substituted Si-based clathrates, Ba8AuGa13Si32 and Ba6A2AuGaxSi45−x (A = Sr, Eu, x = 13, 14), were experimentally and theoretically investigated. The polycrystalline samples of the Au-substituted Si-based clathrates were prepared by using the spark plasma sintering technique. The electronic structure of Ba6A2AuGa13Si32 was theoretically calculated by ab initio calculations,...
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