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The X-ray crystal structures of trigonal silver(I) cyclodextrin complexes of introverted bidentate sulfur (1) and phosphorus (2) ligands give a clear indication on how a cyclodextrin-included ligand may bind in a ditopic fashion both the encapsulated metal ion and the cyclodextrin inner wall. In the solid state, the silver-coordinated water molecule of complex [Ag(H 2 O)(1)]BF 4 induces...
The reaction of 2,3-bis (2,2′-bipyridyl) quinoxaline (L) with ruthenium terpyridine (tpy) trichloride in ethanol containing N-ethyl- morpholine afforded [LRu (tpy) , PF 6 ] 2 (1) and the η 5 -μ-chloro complex [LRu (Cl) tpy, PF 6 ] (2) , as major and minor products, respectively, and recovered L. The structure of 1 was confirmed by 1 H NMR spectroscopic and X-ray...
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