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In this study we synthesized medium-band gap, two-dimensional (2-D) conjugated polymers comprising electron-rich benzo[1,2-b:4,5-b′]dithiophene (BDT) units presenting conjugated thiophene (T) side chains and electron-deficient alkoxy-modified 2,1,3-benzooxadiazole (BO) moieties. We introduced various solubilizing substituents—linear alkyl, alkoxy, and alkythio units—on the thiophene side chains to...
The primary aim of this paper is to explore the influence of the number of CH 2 groups per –(CH 2 ) n OCOO– repeat unit (Num c ) on the properties of poly(alkylene carbonate)s. A series of poly(alkylene carbonate)s with different Num c , including PTMC (Num c = 3), PTeMC (Num c = 4), PPMC (Num c = 5), PHMC (Num c = 6) and...
Poly(6-[4-(4-cyanophenylazo)phenoxy]x-methylene methacrylate) (P x , x is 2 or 6) were synthesized and used to study the texture of side-chain liquid crystalline polymers (SCLCPs) after photoinduced orientation. With increasing temperature of irradiated P 2 film up to 125 o C, just above its T g , 123 o C, a banded texture was observed for SCLCPs under polarized...
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