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A novel hybrid organic–inorganic photocurable sol–gel material based on tantalum ethoxide and 3-trimethoxysilylpropylmethacrylate has been developed, characterised and used in the fabrication of optical waveguides and three-dimensional woodpile structures employing the single and two-photon polymerisation techniques, respectively. Single mode waveguides operating at 1310 and 1550nm have been fabricated,...
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