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We study the dynamic interplay as ${\rm PH}_{3}$ interacts at room temperature to contribute electrons to nanostructure modified p and n-type porous silicon (PS) interfaces. A nanopore coated microporous interface is treated to form ${\rm TiO}_{2}$ , ${\rm SnO}_{x}$ , ${\rm Cu}_{x}{\rm O}$ , and ${\rm Au}_{x}{\rm O}~(x\gg 1)$ nanostructured centers deposited in fractional coverage on the PS...
A simple method is presented to generate pillared and uniformly spaced nano-needle arrays formed by electrochemical modification of nano-walled, densely packed, pore structures with pore diameters that have minimum variation. Needle structures generated in a single etch procedure are between three and four micrometers tall and taper to points 10 nm or less in diameter. The tip-to-tip spacing is found...
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