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In this study, we report the synthesis of benzene‐glycol nucleic acids and studies of their biophysical and biological properties. Using (S)‐mandelic acid as the starting material, we prepared phosphoramidite units for the synthesis of benzene‐glycol nucleic acids. The benzene‐glycol moieties effectively replace the sugar groups ordinarily found in DNA and RNA monomers. Oligonucleotides (ONs) containing...
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