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A tandem three‐component C−H bond addition involving the activation of an inert C(sp3)−H bond is reported. The process enables the direct regioselective synthesis of 1,2‐difunctionalized arenes with the formation of C(sp3)− and C(sp2)−C(arene) bonds. 2‐Iodobenzoic acid derivatives behave as masked bifunctional reagent (BFR) and react with 2‐pyridyl‐methyl sulfoximine (MPyS) protected aliphatic acids...
A tandem three‐component C−H bond addition involving the activation of an inert C(sp3)−H bond is reported. The process enables the direct regioselective synthesis of 1,2‐difunctionalized arenes with the formation of C(sp3)− and C(sp2)−C(arene) bonds. 2‐Iodobenzoic acid derivatives behave as masked bifunctional reagent (BFR) and react with 2‐pyridyl‐methyl sulfoximine (MPyS) protected aliphatic acids...
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