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Acetate adsorbs on Pd(111) as a disordered overlayer. We have used a recently developed LEED I–V technique that allows the structure of disordered molecular overlayers to be examined to determine the structure of acetate adsorbed on Pd(111). Our experimental results are compared with plane-wave density functional theory calculations. The calculated and observed adsorption geometries are in excellent...
The structure of formate species adsorbed on Pd(111) has been determined using low-energy electron diffraction (LEED). The presence of formate species on the Pd(111) surface was established using reflection-absorption infrared spectroscopy (RAIRS). The oxygen atoms of the formate species were found to be adsorbed over surface palladium atoms with the OCO plane perpendicular to the surface. The CO...
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